Physical Chemistry

Addition and Elimination Reactions of Aliphatic Compounds by C.H. Bamford

By C.H. Bamford

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Extra info for Addition and Elimination Reactions of Aliphatic Compounds

Example text

8 X lo-' (25) aq. 273 (25) aq. 114 (25) aq. 8 (0) aq. 141 142 142 142 142 144 I45 144 145 144 145 143 146 146 146 147 Containing 10%. 20%. or 40% water. Containing sodium acetate to prevent acid-catalysed reaction. mole-'. LiCI-catalysed. mole-'. 0 kcal. 85. Relative to ethylene (competition rates). mole-'. mole-'. 9 kcalmole-'. mole-'. 1 Kinetic expression is in fact very complex. mole-I. mole-I. 4-trimethyl- 1- and 2-pentenes; apparently the former isomer was predominant in the mixture used. 'I Reaction follows the kinetics of eqn.

Mole-'. 9 kcalmole-'. mole-'. 1 Kinetic expression is in fact very complex. mole-I. mole-I. 4-trimethyl- 1- and 2-pentenes; apparently the former isomer was predominant in the mixture used. 'I Reaction follows the kinetics of eqn. 3); X 2 refers to the second-order process. The data in ref. I03 contains results obtained cissuming a pure second-order reaction. A :S * = -28eu. 5 k ~ a l . mole-';AS-t=-27eu. 083 (eqn. 2 1 ). mole-'. 1 truns-n-3-Undecene. 7 truns-n-4-Undecene. 7 cis-n-5-Undecene. mole-I, ASt.

Or 40% water. Containing sodium acetate to prevent acid-catalysed reaction. mole-'. LiCI-catalysed. mole-'. 0 kcal. 85. Relative to ethylene (competition rates). mole-'. mole-'. 9 kcalmole-'. mole-'. 1 Kinetic expression is in fact very complex. mole-I. mole-I. 4-trimethyl- 1- and 2-pentenes; apparently the former isomer was predominant in the mixture used. 'I Reaction follows the kinetics of eqn. 3); X 2 refers to the second-order process. The data in ref. I03 contains results obtained cissuming a pure second-order reaction.

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